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Electron microscope and microprobe analysis of chlorite–mica stacks in the wenlock turbidites, mid Wales, U.K.

By: Dimberline, Andrew J.
Material type: ArticleArticleDescription: 299-306pp ; Illustration.Subject(s): Sedimentary petrology | Chlorite group | SEM data | Clastic rock | Petrology | Origin of chlorite - Mica stocks - Wales - United Kingdom In: Geological magazine : Vol. 123 Iss. 1-6 Year. 1986Summary: Chlorite–mica stacks in the Wenlock turbidites have been studied using backscattered electron microscopy and electron microprobe analysis, combined with thin-section work and bulk rock chemical analysis. The stacks occur in fine sandstones and silt–mud turbidites and range in length from < 30 μm to 1.5 mm. They consist of interlayered packets of Fe-rich chlorite and mica. Combined textural and chemical data suggest that many of the stacks represent altered detrital biotite micas. A four-stage alteration sequence is proposed: (1) Subaerial alteration of biotite, in the source area, to interlayered biotite–hydrobiotite/vermiculite. (2) Post-depositional collapse of vermiculite to form a mica phase under conditions of high K+/H+ in the sediment pore waters. (3) Decrease in K+/H+ ratio, possibly due to H+ build up in the fermentation zone, causing alteration of biotite layers to chlorite. (4) Kinking of the stacks and pressure solution of chlorite early in the development of cleavage.
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Bound Journal Collection 550 GEO (Browse shelf) Available 002533

Chlorite–mica stacks in the Wenlock turbidites have been studied using backscattered electron microscopy and electron microprobe analysis, combined with thin-section work and bulk rock chemical analysis. The stacks occur in fine sandstones and silt–mud turbidites and range in length from < 30 μm to 1.5 mm. They consist of interlayered packets of Fe-rich chlorite and mica.

Combined textural and chemical data suggest that many of the stacks represent altered detrital biotite micas. A four-stage alteration sequence is proposed:

(1) Subaerial alteration of biotite, in the source area, to interlayered biotite–hydrobiotite/vermiculite.

(2) Post-depositional collapse of vermiculite to form a mica phase under conditions of high K+/H+ in the sediment pore waters.

(3) Decrease in K+/H+ ratio, possibly due to H+ build up in the fermentation zone, causing alteration of biotite layers to chlorite.

(4) Kinking of the stacks and pressure solution of chlorite early in the development of cleavage.

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